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  • Title: Palladium-catalyzed cyclization of unsaturated beta-amino alcohols: a new access to enantiopure bicyclic oxazolidines.
    Author: Alladoum J, Vrancken E, Mangeney P, Roland S, Kadouri-Puchot C.
    Journal: Org Lett; 2009 Aug 20; 11(16):3746-9. PubMed ID: 19719207.
    Abstract:
    Chiral unsaturated beta-amino alcohols possessing a dialkylamino function cyclize in the presence of Pd(II) catalysts and reoxidants to afford enantiopure bicyclic oxazolidines with total regio- and stereocontrol. The scope and limitations of this transformation have been studied.
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