These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: RPM3: a multifunctional microporous MOF with recyclable framework and high H2 binding energy.
    Author: Lan A, Li K, Wu H, Kong L, Nijem N, Olson DH, Emge TJ, Chabal YJ, Langreth DC, Hong M, Li J.
    Journal: Inorg Chem; 2009 Aug 03; 48(15):7165-73. PubMed ID: 19722690.
    Abstract:
    A microporous metal organic framework structure, Zn(2)(bpdc)(2)(bpee).2DMF (DMF: N,N-dimethylformamide), has been synthesized via solvothermal reactions. The compound is a new member of the RPM series (RPM = Rutgers Recyclable Porous Material) that possesses a flexible and recyclable three-dimensional framework containing one-dimensional channels. It exhibits interesting and multifold functionality, including porosity, commensurate adsorption for hydrocarbons, high hydrogen binding energy (determined by isosteric heats of hydrogen adsorption and confirmed by van der Waals density functional calculations) as a result of multifold binding to aromatic ligands (determined by IR spectroscopy), strong photoluminescence emission, and reversible fluorescence quenching properties.
    [Abstract] [Full Text] [Related] [New Search]