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  • Title: Growth of ZnO nanowires catalyzed by size-dependent melting of Au nanoparticles.
    Author: Petersen EW, Likovich EM, Russell KJ, Narayanamurti V.
    Journal: Nanotechnology; 2009 Oct 07; 20(40):405603. PubMed ID: 19738315.
    Abstract:
    We present a general approach to growing ZnO nanowires on arbitrary, high melting point (above 970 degrees C) substrates using the vapor-liquid-solid (VLS) growth mechanism. Our approach utilizes the melting point reduction of sufficiently small (5 nm diameter) Au particles to provide a liquid catalyst without substrate interaction. Using this size-dependent melting effect, we demonstrate catalytic VLS growth of ZnO nanowires on both Ti and Mo foil substrates with aspect ratios in excess of 1000:1. Transmission electron microscopy shows the nanowires to be single-crystalline, and photoluminescence spectra show high-quality optical properties. We believe this growth technique to be widely applicable to a variety of substrates and material systems.
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