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  • Title: Rational design and synthesis of ansa-adenosines as potential antitumor agents.
    Author: Muranaka K, Ichikawa S, Matsuda A.
    Journal: Nucleic Acids Symp Ser (Oxf); 2009; (53):5-6. PubMed ID: 19749232.
    Abstract:
    Synthesis of benzoquinone ansa-adenosines, which are rationally designed as Hsp90 inhibitors by extracting and fusing a natural substrate, ATP, and a natural product, geldanamycin, was described. This simpler scaffold design provides practical synthesis of a set of analogs and demonstrates synthetic innovation.
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