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  • Title: Asymmetric meso-aziridine ring-opening reactions using a chiral zirconium catalyst.
    Author: Seki K, Yu R, Yamazaki Y, Yamashita Y, Kobayashi S.
    Journal: Chem Commun (Camb); 2009 Oct 14; (38):5722-4. PubMed ID: 19774248.
    Abstract:
    A chiral zirconium catalyst prepared from Zr(O(t)Bu)4 and a chiral tridentate BINOL was found to be effective for asymmetric meso-aziridine ring-opening reactions with aniline derivatives. The N-benzhydryl group on the product obtained was easily cleaved to give the corresponding amine in high yield under reductive conditions.
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