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  • Title: The synthesis of allenes by Cu(I)-catalyzed regio- and stereoselective reduction of propargylic carbonates with hydrosilanes.
    Author: Zhong C, Sasaki Y, Ito H, Sawamura M.
    Journal: Chem Commun (Camb); 2009 Oct 21; (39):5850-2. PubMed ID: 19787118.
    Abstract:
    Cu(I)-catalyzed anti-S(N)2'-type reduction of internal propargylic carbonates with hydrosilanes affords various di- and trisubstituted allenes with high regioselectivities; the reactions are compatible with functional groups and work efficiently for the synthesis of optically-active allenes.
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