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  • Title: Synthesis of highly substituted naphthalene and anthracene derivatives by rhodium-catalyzed oxidative coupling of arylboronic acids with alkynes.
    Author: Fukutani T, Hirano K, Satoh T, Miura M.
    Journal: Org Lett; 2009 Nov 19; 11(22):5198-201. PubMed ID: 19831368.
    Abstract:
    The rhodium-catalyzed oxidative 1:2 coupling reactions of arylboronic acids with alkynes effectively proceeds in the presence of a copper-air oxidant to produce the corresponding annulated products. Of special note, anthracene derivatives can be obtained selectively from 2-naphthylboronic acids.
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