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  • Title: Modular synthesis of heterobimetallic salen structures using metal templation.
    Author: Castilla AM, Curreli S, Escudero-Adán EC, Belmonte MM, Benet-Buchholz J, Kleij AW.
    Journal: Org Lett; 2009 Nov 19; 11(22):5218-21. PubMed ID: 19845369.
    Abstract:
    A modular and general synthetic method is disclosed for nonsymmetrical heterobimetallic bis-salphen structures starting from a series of synthetically convenient monometalated triimine precursors. This methodology permits the introduction of various combinations of metal ions within the bis-salphen framework potentially useful in multifunctional materials.
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