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  • Title: Formation of tetrameric water clusters driven by a cavitand template.
    Author: Massera C, Melegari M, Ugozzoli F, Dalcanale E.
    Journal: Chem Commun (Camb); 2010 Jan 07; 46(1):88-90. PubMed ID: 20024302.
    Abstract:
    We describe an innovative approach to the generation of tetrameric water clusters in the solid state. The specific H-bond pattern induced by the tetraphosphonate cavitand template via its rigidly preorganized P=O acceptor groups leads to the exclusive formation of the unique cyclic homodromic water tetramer of C(4) symmetry.
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