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  • Title: Total synthesis of uniflorine A, casuarine, australine, 3-epi-australine, and 3,7-di-epi-australine from a common precursor.
    Author: Ritthiwigrom T, Willis AC, Pyne SG.
    Journal: J Org Chem; 2010 Feb 05; 75(3):815-24. PubMed ID: 20028000.
    Abstract:
    A flexible method for the diastereoselective total synthesis of the pyrrolizidine alkaloids uniflorine A, casuarine, australine, and 3-epi-australine and the unnatural epimer 3,7-di-epi-australine from a common chiral 2,5-dihydropyrrole precursor is described.
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