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  • Title: Amine-induced Michael/Conia-ene cascade reaction: application to a formal synthesis of (+/-)-Clavukerin A.
    Author: Li W, Liu X, Zhou X, Lee CS.
    Journal: Org Lett; 2010 Feb 05; 12(3):548-51. PubMed ID: 20028120.
    Abstract:
    An efficient and versatile amine-induced Michael/Conia-ene cascade cyclization reaction has been developed for establishing 6,6- and 5,7-bicyclic fused carbocycles with simple acyclic beta-ketoesters as the substrates in one-pot condition and this new cyclization method has been successfully utilized in a formal synthesis of (+/-)-Clavukerin A.
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