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Title: Synthetic approach to polysubstituted furans: an efficient addition/oxidative cyclization of alkynoates and 1,3-dicarbonyl compounds. Author: Liu W, Jiang H, Zhang M, Qi C. Journal: J Org Chem; 2010 Feb 05; 75(3):966-8. PubMed ID: 20055376. Abstract: A novel and reliable method for the direct construction of polysubstituted furans is reported. The key transformation involves Sn(II)- and Cu(I)-involved addition/oxidative cyclization of alkynoates and 1,3-dicarbonyl compounds in the presence of 2,3-dichloro-5,6-dicyanobenzoquinone.[Abstract] [Full Text] [Related] [New Search]