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Title: Pd-catalyzed oxidative coupling with organometallic reagents via C-H activation. Author: Sun CL, Li BJ, Shi ZJ. Journal: Chem Commun (Camb); 2010 Feb 07; 46(5):677-85. PubMed ID: 20087486. Abstract: Direct selective palladium catalyzed C-H functionalization has become a highly attractive strategy in organic synthesis and represents a highly desirable goal. Compared with cross-coupling reactions of C-H bonds with aryl or alkyl halides/pseudohalides, the strategy of cross-coupling reactions of C-H bonds with organometallic reagents is of great significance and obvious advantages. This feature article provides a comprehensive summary of recent advances and an intensive analysis on Pd-catalyzed C-H activation and oxidative coupling with various organometallic reagents.[Abstract] [Full Text] [Related] [New Search]