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  • Title: Copper-free cycloaddition of azide and alkyne in crystalline state facilitated by arene-perfluoroarene interactions.
    Author: Ni BB, Wang C, Wu H, Pei J, Ma Y.
    Journal: Chem Commun (Camb); 2010 Feb 07; 46(5):782-4. PubMed ID: 20087519.
    Abstract:
    Facilitated by arene-perfluoroarene interactions, a 1,3-dipolar cycloaddition between azide and alkyne proceeded in the crystals at room temperature in the absence of a copper(I) catalyst, and the reaction was confirmed to be a highly regioselective process giving the 1,4-triazole product.
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