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  • Title: Rapid assembly of the salvileucalin B norcaradiene core.
    Author: Levin S, Nani RR, Reisman SE.
    Journal: Org Lett; 2010 Feb 19; 12(4):780-3. PubMed ID: 20088588.
    Abstract:
    Preparation of the polycyclic core of the cytotoxic natural product salvileucalin B is described. The key feature of this synthetic strategy is a copper-catalyzed intramolecular arene cyclopropanation to provide the central norcaradiene. These studies lay the foundation for continued investigations toward an enantioselective total synthesis of 1.
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