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  • Title: Enantioselective desymmetrizing palladium catalyzed carbonylation reactions: the catalytic asymmetric synthesis of quaternary carbon center containing 1,3-dienes.
    Author: Byrne SJ, Fletcher AJ, Hebeisen P, Willis MC.
    Journal: Org Biomol Chem; 2010 Feb 21; 8(4):758-60. PubMed ID: 20135030.
    Abstract:
    A desymmetrization protocol has been used to develop a palladium catalyzed enantioselective carbonylation process. Achiral cyclic bis-alkenyltriflates are converted to their corresponding monoester derivatives with selectivities of up to 96% ee.
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