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  • Title: Omega-ethylenic allylic substrates as alternatives to cyclic substrates in copper- and iridium-catalyzed asymmetric allylic alkylation.
    Author: Giacomina F, Riat D, Alexakis A.
    Journal: Org Lett; 2010 Mar 19; 12(6):1156-9. PubMed ID: 20166707.
    Abstract:
    A new strategy to access highly enantioenriched cyclic compounds (up to 98%) is proposed using omega-ethylenic allylic substrates through a one-pot asymmetric allylic alkylation and ring-closing metathesis. Such starting compounds can be seen as synthetic equivalents of cyclic allylic substrates.
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