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  • Title: Total regioselective transformation of aromatic aziridine 2-carboxamides into 2-aminoamides promoted by active manganese.
    Author: Concellón JM, Rodríguez-Solla H, Del Amo V, Díaz P.
    Journal: J Org Chem; 2010 Apr 02; 75(7):2407-10. PubMed ID: 20196575.
    Abstract:
    A novel, totally regioselective transformation of aromatic N-4-methoxyphenylaziridine 2-carboxamides into 2-aminoamides promoted by active manganese (Mn*) is reported. alpha-Amino ketones can be readily obtained by reaction of morpholine-derived 2-aminoamides with organolithium compounds.
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