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  • Title: Total synthesis of proposed auranthine.
    Author: Kshirsagar UA, Puranik VG, Argade NP.
    Journal: J Org Chem; 2010 Apr 16; 75(8):2702-5. PubMed ID: 20302381.
    Abstract:
    Starting from CBz-protected glutamic anhydride and Boc-protected o-aminobenzyl amine, the first total synthesis of proposed structure of auranthine has been reported. An intramolecular aza-Wittig reaction involving a lactam carbonyl group that delivered the diazepine core unit was the key step in the synthesis.
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