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  • Title: Determination of absolute configuration of trimeric indole alkaloid, psychotrimine, by first asymmetric total synthesis.
    Author: Takahashi N, Ito T, Matsuda Y, Kogure N, Kitajima M, Takayama H.
    Journal: Chem Commun (Camb); 2010 Apr 14; 46(14):2501-3. PubMed ID: 20309475.
    Abstract:
    The first asymmetric total synthesis of psychotrimine, a trimeric indole alkaloid, was accomplished via an asymmetric Ireland-Claisen rearrangement to construct a chiral quaternary carbon center, thereby establishing the absolute configuration of psychotrimine.
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