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  • Title: Selective detection of trace Cr3+ in aqueous solution by using 5,5'-dithiobis (2-nitrobenzoic acid)-modified gold nanoparticles.
    Author: Dang YQ, Li HW, Wang B, Li L, Wu Y.
    Journal: ACS Appl Mater Interfaces; 2009 Jul; 1(7):1533-8. PubMed ID: 20355957.
    Abstract:
    A simply prepared gold nanoparticle-based sensor, 5,5'-dithiobis (2-nitrobenzoic acid) (DTNBA)-modified gold nanoparticles, was prepared to explore the sensitive and selective detection of metal ions using a colorimetric technique. The selective detection of trace levels (93.6 ppb) Cr3+ in aqueous solution was achieved over 15 other metal ions. The functionalized gold nanoparticles became aggregated in solution in the presence of Cr3+ by an ion-templated chelation process, which caused an easily measurable change in the extinction spectrum of the particles and provided an inherently sensitive method for Cr3+ detection in aqueous solution.
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