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  • Title: Single-ion magnets based on mononuclear lanthanide complexes with chiral Schiff base ligands [Ln(FTA)3L] (Ln = Sm, Eu, Gd, Tb and Dy).
    Author: Li DP, Wang TW, Li CH, Liu DS, Li YZ, You XZ.
    Journal: Chem Commun (Camb); 2010 May 07; 46(17):2929-31. PubMed ID: 20386826.
    Abstract:
    A series of mononuclear lanthanide complexes with chiral Schiff base ligands [Ln(FTA)(3)L] [Ln = Dy(1), Sm(2), Eu(3), Gd(4), and Tb(5), L = (S,S)-2,2'-Bis(4-benzyl-2-oxazoline)] were synthesized and characterized. Among these complexes, complex 1 represents the first example of mononuclear lanthanide complexes displaying single-ion magnet behavior and ferroelectricity.
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