These tools will no longer be maintained as of December 31, 2024. Archived website can be found here. PubMed4Hh GitHub repository can be found here. Contact NLM Customer Service if you have questions.


Pubmed for Handhelds

PUBMED FOR HANDHELDS

Search MEDLINE/PubMed

  • Title: The functionalisation of ruthenium(II) and osmium(II) alkenyl complexes with amine- and alkoxy-terminated dithiocarbamates.
    Author: Naeem S, Ogilvie E, White AJ, Hogarth G, Wilton-Ely JD.
    Journal: Dalton Trans; 2010 May 07; 39(17):4080-9. PubMed ID: 20390171.
    Abstract:
    The complex cis-[RuCl(2)(dppm)(2)] reacts with the amine-terminated dithiocarbamates KS(2)CN(CH(2)CH(2)NEt(2))(2) and KS(2)CN(CH(2)CH(2)CH(2)NMe(2))(2) to form the compounds [Ru{S(2)CN(CH(2)CH(2)NEt(2))(2)}(dppm)(2)](+) and [Ru{S(2)CN(CH(2)CH(2)CH(2)NMe(2))(2)}(dppm)(2)](+), respectively. The methoxy-terminated dithiocarbamate compound [Ru{S(2)CN(CH(2)CH(2)OMe)(2)}(dppm)(2)](+) was also prepared from the same precursor using KS(2)CN(CH(2)CH(2)OMe)(2). The alkenyl complexes [RuRCl(CO)(BTD)(PPh(3))(2)] (R = CH=CHBu(t), CH=CHC(6)H(4)Me-4, CH=CHCPh(2)OH), [Ru(C(C[triple bond]CBu(t))=CHBu(t))Cl(CO)(PPh(3))(2)] and [Os(CH=CHC(6)H(4)Me-4)Cl(CO)(BTD)(PPh(3))(2)] also react cleanly with KS(2)CN(CH(2)CH(2)CH(2)NMe(2))(2) and KS(2)CN(CH(2)CH(2)NEt(2))(2) to yield [MR{S(2)CN(CH(2)CH(2)CH(2)NMe(2))(2)}(CO)(PPh(3))(2)] and [MR{S(2)CN(CH(2)CH(2)NEt(2))(2)}(CO)(PPh(3))(2)], respectively. In a similar fashion, the compounds [RuR{S(2)CN(CH(2)CH(2)OMe(2))(2)}(CO)(PPh(3))(2)] (R = CH=CHBu(t), CH=CHC(6)H(4)Me-4, C(C[triple bond]CBu(t))=CHBu(t)) were also prepared. Treatment of [Ru(CH=CHBu(t)){S(2)CN(CH(2)CH(2)CH(2)NMe(2))(2)}(CO)(PPh(3))(2)] and [Ru{S(2)CN(CH(2)CH(2)NEt(2))(2)}(dppm)(2)](+) with trifluoroacetic acid affords the ammonium complexes [Ru(CH=CHBu(t)){S(2)CN(CH(2)CH(2)CH(2)NHMe(2))(2)}(CO)(PPh(3))(2)](2+) and [Ru{S(2)CN(CH(2)CH(2)NHEt(2))(2)}(dppm)(2)](2+), while the same reagent generates the tricationic vinylcarbene complex [Ru(=CHCH=CPh(2)){S(2)CN(CH(2)CH(2)CH(2)NHMe(2))(2)}(CO)(PPh(3))(2)](3+) through loss of water from [Ru(CH=CHCPh(2)OH){S(2)CN(CH(2)CH(2)CH(2)NMe(2))(2)}(CO)(PPh(3))(2)]. The structures of [Ru{S(2)CN(CH(2)CH(2)OMe)(2)}(dppm)(2)]PF(6) and [Ru(CH=CHC(6)H(4)Me-4){S(2)CN(CH(2)CH(2)OMe)(2)}(CO)(PPh(3))(2)] were determined crystallographically.
    [Abstract] [Full Text] [Related] [New Search]