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  • Title: Highly enantioselective relay catalysis in the three-component reaction for direct construction of structurally complex heterocycles.
    Author: Wang C, Han ZY, Luo HW, Gong LZ.
    Journal: Org Lett; 2010 May 21; 12(10):2266-9. PubMed ID: 20405953.
    Abstract:
    A highly enantioselective three-component cascade reaction, consisting of an enantioselective [4+2] cycloaddition reaction catalyzed by chiral phosphoric acid and a subsequent catalytic intramolecular hydroamination by gold(I) complex, provides a unique method to access structurally diverse julolidine derivatives in high optical purity.
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