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  • Title: Catalytic enantioselective Mannich-type reaction with beta-phenyl sulfonyl acetonitrile.
    Author: González PB, Lopez R, Palomo C.
    Journal: J Org Chem; 2010 Jun 04; 75(11):3920-2. PubMed ID: 20426457.
    Abstract:
    The organocatalytic addition of beta-phenyl sulfonyl acetonitrile 1 to either N-Boc-protected alpha-amido sulfones or imines allowed the synthesis of enantioenriched alpha-unsubstituted beta-amino nitriles through a Mannich-type reaction.
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