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  • Title: PbS/PbSe structures with core-shell type morphology synthesized from PbS nanocrystals.
    Author: Koktysh DS, McBride JR, Dixit SK, Feldman LC, Rosenthal SJ.
    Journal: Nanotechnology; 2007 Dec 12; 18(49):495607. PubMed ID: 20442480.
    Abstract:
    Colloidal PbS/PbSe nanostructures with core-shell type morphology have been synthesized for the first time using a simple chemical procedure where template PbS nanocrystals (NCs) were treated with Se solution in tributylphosphine at elevated temperature. The Se-coated PbS NCs were structurally and optically characterized by high resolution transmission electron microscopy (HRTEM), x-ray diffraction (XRD), Rutherford backscattering spectrometry (RBS) analysis, absorption and photoluminescence (PL) spectroscopy. Synthesized PbS/PbSe structures can be of particular importance in photovoltaic applications where fabrication of heterostructures with compositional modulation on the nanometer scale is essential.
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