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  • Title: Synthesis of the bis-spiroacetal C25-C40 moiety of the antimitotic agent spirastrellolide B using a bis-dithiane deprotection/spiroacetalisation sequence.
    Author: Chen JL, Brimble MA.
    Journal: Chem Commun (Camb); 2010 Jun 14; 46(22):3967-9. PubMed ID: 20445924.
    Abstract:
    Use of a bis-dithiane deprotection-tandem bis-spiroacetalisation sequence was key to the successful synthesis of the [5,6,6]-bis-spiroacetal of the antimitotic agent spirastrellolide B, achieved in a highly convergent fashion involving successive dithiane alkylations.
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