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  • Title: Unprecedented cubane-type silver cluster with a novel phosphinite functionalized N-heterocyclic carbene ligand.
    Author: Raynal M, Liu X, Pattacini R, Vallée C, Olivier-Bourbigou H, Braunstein P.
    Journal: Dalton Trans; 2009 Sep 21; (35):7288-93. PubMed ID: 20449173.
    Abstract:
    A novel heterodifunctional phosphinite imidazolium salt was synthesized and reacted with Ag(I) to afford an unusual tetrasilver cubane-type cluster with two P-NHC ligands bridging between the Ag(I) centres of opposite Ag(2)I(2) faces.
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