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  • Title: Allenamide hydro-hydroxyalkylation: 1,2-amino alcohols via ruthenium-catalyzed carbonyl anti-aminoallylation.
    Author: Zbieg JR, McInturff EL, Krische MJ.
    Journal: Org Lett; 2010 Jun 04; 12(11):2514-6. PubMed ID: 20459077.
    Abstract:
    Exposure of alcohols to allenamides in the presence of RuHCl(CO)(PPh(3))(3) and dippf [dippf = bis(diisopropylphosphino)ferrocene] results in hydrogen transfer to generate aldehyde-allylruthenium pairs, which engage in C-C coupling to form products of carbonyl aminoallylation as single anti-diastereomers.
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