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  • Title: Amine-promoted synthesis of vinyl aziridines.
    Author: Armstrong A, Pullin RD, Jenner CR, Scutt JN.
    Journal: J Org Chem; 2010 May 21; 75(10):3499-502. PubMed ID: 20465292.
    Abstract:
    N-Unsubstituted vinyl aziridines were synthesized via an amine-promoted regioselective nucleophilic aziridination of alpha,beta,gamma,delta-unsaturated carbonyl compounds. The reaction is completely regioselective (>95: 5) for the alpha,beta-alkene and completely diastereoselective, affording the trans-vinyl aziridine in moderate-to-good yields.
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