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  • Title: Synthesis of bimetallic uranium and neptunium complexes of a binucleating macrocycle and determination of the solid-state structure by magnetic analysis.
    Author: Arnold PL, Potter NA, Magnani N, Apostolidis C, Griveau JC, Colineau E, Morgenstern A, Caciuffo R, Love JB.
    Journal: Inorg Chem; 2010 Jun 21; 49(12):5341-3. PubMed ID: 20503974.
    Abstract:
    Syntheses of the bimetallic uranium(III) and neptunium(III) complexes [(UI)(2)(L)], [(NpI)(2)(L)], and [{U(BH(4))}(2)(L)] of the Schiff-base pyrrole macrocycles L are described. In the absence of single-crystal structural data, fitting of the variable-temperature solid-state magnetic data allows the prediction of polymeric structures for these compounds in the solid state.
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