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  • Title: NMR (1D and 2D) and X-ray crystallographic studies of Ni(II) complex with N-(2-mercaptophenyl)-4-methoxysalicylideneimine and triphenylphosphine.
    Author: Muthu Tamizh M, Varghese B, Endo A, Karvembu R.
    Journal: Spectrochim Acta A Mol Biomol Spectrosc; 2010 Oct 01; 77(2):411-8. PubMed ID: 20594904.
    Abstract:
    Mononuclear nickel(II) complex, viz. [Ni(L)(PPh(3))] (where L is dianion of N-(2-mercaptophenyl)-4-methoxysalicylideneimine) has been synthesized and characterized by means of elemental analysis, electronic, IR and NMR [(1)H, (13)C{(1)H} and (31)P{(1)H}, DEPT, (1)H-(1)H COSY, ge-HSQC, ge-HMBC] spectroscopic techniques. Structural analysis of the complex by single crystal X-ray crystallography indicated the presence of square planar coordination geometry (ONSP) about nickel. One of the phenyl rings of triphenylphosphine involve in C-H...pi interactions with H6b, H13 and H32 to form a three dimensional network which stabilizes the structure of complex.
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