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  • Title: Diastereoselective hydrophosphonylation of imines using (R,R)-TADDOL phosphite. Asymmetric synthesis of alpha-aminophosphonic acid derivatives.
    Author: Palacios F, Olszewski TK, Vicario J.
    Journal: Org Biomol Chem; 2010 Oct 07; 8(19):4255-8. PubMed ID: 20672154.
    Abstract:
    Efficient synthesis of alpha-aminophosphonic acid derivatives is achieved, the key step being a diastereoselective hydrophosphonylation of N-diphenylphosphinyl imines using a readily available chiral cyclic (R,R)-TADDOL-phosphite derived from inexpensive natural tartaric acid.
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