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  • Title: Pd-catalyzed carbonylative conjugate addition of dialkylzinc reagents to unsaturated carbonyls.
    Author: Custar DW, Le H, Morken JP.
    Journal: Org Lett; 2010 Sep 03; 12(17):3760-3. PubMed ID: 20687574.
    Abstract:
    The Pd-catalyzed addition of organozinc reagents to unsaturated carbonyls in the presence of carbon monoxide provides 1,4-diketones in good yield. The reaction was studied with a number of substituted cyclic and acyclic ketones as well as alpha,beta-unsaturated aldehydes.
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