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  • Title: Catalytic enantioselective radical cyclization via regiodivergent epoxide opening.
    Author: Gansäuer A, Shi L, Otte M.
    Journal: J Am Chem Soc; 2010 Sep 01; 132(34):11858-9. PubMed ID: 20687604.
    Abstract:
    A catalytic enantio- and diastereoselective radical cyclization using a regiodivergent epoxide opening (REO) for radical generation is described. It is demonstrated for the first time that the diastereoselectivity of cyclizations of acyclic radicals can be controlled catalytically. Building blocks for important applications in stereoselective synthesis are readily accessed.
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