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  • Title: Copper(I) complexes with N-(diisopropoxythiophosphoryl)thiobenzamide PhC(S)NHP(S)(OiPr)2.
    Author: Babashkina MG, Safin DA, Fayon F, Rakhmatullin AI, Sokolov FD, Klein A, Krivolapov DB, Pape T, Hahn FE, Kozlowski H.
    Journal: Dalton Trans; 2010 Sep 21; 39(35):8261-8. PubMed ID: 20689886.
    Abstract:
    Reaction of the potassium salt of N-thiophosphorylthiobenzamide PhC(S)NHP(S)(OiPr)(2) (HL) with CuI in aqueous EtOH leads to the tetranuclear [Cu(4)L(4)] and the polynuclear [KCuL(2)](n) complexes, while the same reactions using the lithium or sodium salts of HL exclusively lead to the tetramer [Cu(4)L(4)]. Reaction of KL with the mixture of CuI and 2,2'-bipyridine (bpy) or 1,10-phenanthroline (phen) leads to the mononuclear complexes [Cu(bpy)L] and [Cu(phen)L]. The same complexes were obtained by the reaction of [Cu(4)L(4)] with bpy or phen.
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