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  • Title: Accessing the antipodal series in microbial arene oxidation: a novel diene rearrangement induced by tricarbonyliron(0) complexation.
    Author: Khan MA, Lowe JP, Johnson AL, Stewart AJ, Lewis SE.
    Journal: Chem Commun (Camb); 2011 Jan 07; 47(1):215-7. PubMed ID: 20730137.
    Abstract:
    A cyclohexadiene ligand prepared by microbial arene 1,2-dihydroxylation undergoes spontaneous rearrangement upon complexation to tricarbonyliron(0). Subsequent iron removal affords a novel route to formal arene 2,3-dihydroxylation products enantiomeric to those obtainable by direct microbial arene oxidation.
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