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  • Title: A highly adaptable catalyst/substrate system for the synthesis of substituted chromenes.
    Author: Aponick A, Biannic B, Jong MR.
    Journal: Chem Commun (Camb); 2010 Sep 28; 46(36):6849-51. PubMed ID: 20730147.
    Abstract:
    The gold(I)-catalyzed endo-cyclization of o-(1-hydroxyallyl)phenols to form chromenes is reported. The title compounds are prepared in high yield from readily available substrates. The system tolerates both electron rich and deficient aryl rings and a high degree of substitution on the allyl moiety.
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