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  • Title: Copper-catalyzed olefin aminoacetoxylation.
    Author: Mancheno DE, Thornton AR, Stoll AH, Kong A, Blakey SB.
    Journal: Org Lett; 2010 Sep 17; 12(18):4110-3. PubMed ID: 20735066.
    Abstract:
    A new catalyst system for intramolecular olefin aminoacetoxylation is described. In contrast to previously reported palladium- and copper-catalyzed systems, the conditions outlined in this communication favor piperdine formation with terminal olefin substrates and induce cyclization with traditionally less reactive disubstituted olefins.
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