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  • Title: A concise total synthesis of amphidinolide T2.
    Author: Li H, Wu J, Luo J, Dai WM.
    Journal: Chemistry; 2010 Oct 11; 16(38):11530-4. PubMed ID: 20803588.
    Abstract:
    RCM + AD = T2: In the presence of the C16-methylene group, regioselective ring-closing metathesis (RCM) formed the (12E)-endocyclic double bond, which underwent Os-catalyzed asymmetric dihydroxylation (AD) to give the desired 12,13-diol intermediate required for the total synthesis of amphidinolide T2 in 16 linear steps in 8.0% overall yield.
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