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  • Title: O-silylative Passerini reaction: a new one-pot synthesis of α-siloxyamides.
    Author: Soeta T, Kojima Y, Ukaji Y, Inomata K.
    Journal: Org Lett; 2010 Oct 01; 12(19):4341-3. PubMed ID: 20822154.
    Abstract:
    A new method for the highly effective synthesis of α-siloxyamides is described. The addition of isocyanide to aldehyde proceeded smoothly in the presence of silanol to give the corresponding α-siloxyamides in high yields. A wide range of aldehydes and isocyanides are applicable in this reaction.
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