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Title: Benzotriazol-1-yl-sulfonyl azide for diazotransfer and preparation of azidoacylbenzotriazoles. Author: Katritzky AR, El Khatib M, Bol'shakov O, Khelashvili L, Steel PJ. Journal: J Org Chem; 2010 Oct 01; 75(19):6532-9. PubMed ID: 20825153. Abstract: Benzotriazol-1-yl-sulfonyl azide, a new crystalline, stable, and easily available diazotransfer reagent provides N-(α-azidoacyl)benzotriazoles convenient for N-, O-, C- and S-acylations. The efficient syntheses of various amides, azido protected peptides, esters, ketones and thioesters is reported together with a wide range of azides (including α-azido acids from α- amino acids in partially aqueous conditions) and diazo compounds.[Abstract] [Full Text] [Related] [New Search]