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  • Title: Enantioselective total synthesis of spirofungins A and B.
    Author: Crimmins MT, O'Bryan EA.
    Journal: Org Lett; 2010 Oct 01; 12(19):4416-9. PubMed ID: 20831229.
    Abstract:
    The enantioselective total synthesis of spirofungins A (1) and B (2) is reported in 14 steps over the longest linear sequence. Key steps include the use of thiazolidinethione-mediated aldol reactions to assemble the major fragments and installation of the C1-C6 side chain using a cross metathesis reaction.
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