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  • Title: Cyclic phosphates of formycin.
    Author: Makabe O, Miyadera A, Kinoshita M, Umezawa S.
    Journal: J Antibiot (Tokyo); 1978 May; 31(5):456-67. PubMed ID: 209007.
    Abstract:
    The syntheses of N1- and N2-isopropylformycin (10, 11), formycin 3',5'-cyclic and 2',3'-cyclic phosphate (3,7) and their N-methyl and N-isopropyl derivatives (13, 15, 19, 23) are described. It was observed that substitution at N1 or N2 with a bulky alkyl group or cyclic phosphorylation of the ribose moiety made formycin resistant to adenosine deaminase.
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