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  • Title: Enantioselective Pd-catalyzed hydrogenation of fluorinated imines: facile access to chiral fluorinated amines.
    Author: Chen MW, Duan Y, Chen QA, Wang DS, Yu CB, Zhou YG.
    Journal: Org Lett; 2010 Nov 05; 12(21):5075-7. PubMed ID: 20919725.
    Abstract:
    An enantioselective hydrogenation of simple fluorinated imines has been developed using Pd(OCOCF(3))(2)/(R)-Cl-MeO-BIPHEP as a catalyst, and up to 94% ee was achieved. This method provides an efficient route to enantioenriched fluorinated amines.
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