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  • Title: Ruthenium-catalyzed tertiary amine formation from nitroarenes and alcohols.
    Author: Feng C, Liu Y, Peng S, Shuai Q, Deng G, Li CJ.
    Journal: Org Lett; 2010 Nov 05; 12(21):4888-91. PubMed ID: 20929260.
    Abstract:
    A highly selective ruthenium-catalyzed C-N bond formation was developed by using the hydrogen-borrowing strategy. Various tertiary amines were obtained efficiently from nitroarenes and primary alcohols. The reaction tolerates a wide range of functionalities. A tentative mechanism was proposed for this direct amination reaction of alcohols with nitroarenes.
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