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  • Title: Simple combustion production and characterization of octahydro[60]fullerene with a non-IPR C60 cage.
    Author: Weng QH, He Q, Liu T, Huang HY, Chen JH, Gao ZY, Xie SY, Lu X, Huang RB, Zheng LS.
    Journal: J Am Chem Soc; 2010 Nov 03; 132(43):15093-5. PubMed ID: 20931962.
    Abstract:
    For the first time an easier, operable combustion method is employed for the synthesis of non-IPR fullerene, and an octahydro[60]fullerene with a non-IPR C(60) cage (C(60) isomer (#1809)C(60)) produced by combustion is isolated and characterized by MS, UV-vis, IR, and NMR spectroscopies in combination with DFT calculations. This finding shows that, in addition to chlorine, hydrogen can be an ample cataloreactant for the production of non-IPR fullerene derivatives under such conditions as arc-burning and diffusion combustion.
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