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  • Title: Water-compatible iminium activation: highly enantioselective organocatalytic Michael addition of malonates to α,β-unsaturated enones.
    Author: Mao Z, Jia Y, Li W, Wang R.
    Journal: J Org Chem; 2010 Nov 05; 75(21):7428-30. PubMed ID: 20936828.
    Abstract:
    The highly enantioselective Michael addition of malonates to α,β-unsaturated ketones in water was reported to be catalyzed by a primary-secondary diamine catalyst containing a long alkyl chain. This asymmetric Michael addition process was found to be effective for a variety of α,β-unsaturated ketones.
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