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  • Title: Complete disassembly of carbon disulfide by a ditantalum complex.
    Author: Ballmann J, Yeo A, MacKay BA, van Rijt S, Patrick BO, Fryzuk MD.
    Journal: Chem Commun (Camb); 2010 Dec 14; 46(46):8794-6. PubMed ID: 20959897.
    Abstract:
    The side-on end-on dinitrogen complex [PhP(CH(2)SiMe(2)NPh)(2)Ta](μ-H)(2)(μ-η(2):η(1)-N(2)) reacts with CS(2) with complete cleavage of both C=S double bonds and the formation of [PhP(CH(2)SiMe(2)NPh)(2)Ta](μ-S)(2)(μ-CH(2)), which has two bridging sulfides and a bridging methylene unit. Further reaction with H(2) produces CH(4) and the disulfide complex.
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