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  • Title: Enantioselective conjugate addition of oximes to trisubstituted β-nitroacrylates: an organocatalytic approach to β(2,2)-amino acid derivatives.
    Author: Zhang FG, Yang QQ, Xuan J, Lu HH, Duan SW, Chen JR, Xiao WJ.
    Journal: Org Lett; 2010 Dec 17; 12(24):5636-9. PubMed ID: 21080696.
    Abstract:
    A highly enantioselective organocatalytic intermolecular conjugate addition of oximes to β-nitroacrylates has been developed. The highly functionalized adducts obtained are valuable precursors for asymmetric synthesis, as demonstrated by the synthesis of β(2,2)-amino acids and oxazolidin-2-ones.
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